Dear Prof. Hernández-Luis, (respuesta en castellano más abajo). Find more information on the Altmetric Attention Score and how the score is calculated. Cecilia B. Castells, Leonardo G. Gagliardi, Clara Ràfols, Martı́ Rosés, Elisabeth Bosch. So I mean it is a function of the properties of one solvent. The experimental data shown in these pages are freely available and have been published already in the DDB Explorer Edition.The data represent a small sub list of all … Molecular dynamics simulation results with the OPLS-AA model for methanol. El NaCl es el soluto y la mezcla agua-formamida, por ejemplo, es el solvente. Marc Lavertu, Vincent Darras, Michael D. Buschmann. But as our groups has shown in recent publications, after applying these modifications, it is possible to predict mixtures in quite good agreement with experimental data. Qing-Hai Hao, Gang Xia, Bing Miao, Hong-Ge Tan, Xiao-Hui Niu. : Compressed-Liquid Dielectric Constants and Derived Excess Volumes for Simple Liquid Mixtures: N2 + CH4 and Ar + CH4. 3) The degree of contamination (DOC) by Azure Blue V depended on ε of each solvent and it showed minimum at ε ≈ 7. Ajaya Bhattarai, Sujeet K. Chatterjee, Tarun K. Deo, and Tulasi Prasad Niraula . A. Wieneke. Davidson D.W.: The Dielectric Properties of Methanol and Methanol-D. Can.J.Chem. Zachara, C.C. Flow supercritical synthesis of brucite and magnesian T-O, T-O-T phyllosilicates: an opportunity to tune the structure with the solvent composition. Robert M. Fleming and William G. Clark. Although people have mention "in general" the higher the dielectric constant of the solvent, the higher the solubility of salts in the solvent, there's really been no proper studies about this. J.Chem.Thermodyn. In your original post, you claim that "...I have proven that it influences the ionic association or the primary hydration number, but not the solubility (the solubility product, the increased energy of Gibbs' transference,...)", I would love to see the proofs. Tze Chung Chan, Cherie H. C. Chan, Nga Wun Chang. C. L. de Ligny, P. F. M. Luykx, M. Rehbach, A. The particular case of water. Edgar Galicia-Andrés, Hector Dominguez, László Pusztai, Orest Pizio. Now, if g+/- depends on the T, P and er and we have already set T, P and therefore er, Kps will only depend on ionic parameters (radius, charge and ionic interaction parameters typical of the model used). Single-Crystal Structures of Fully Dehydrated Li,Na–Y. Hu Sik Kim, Sik Young Choi, Woo Taik Lim. Do I need a permission to copy any figure from a research article for my review article? H. Stuart, Th. An extension of the Peng–Robinson equation of state for the correlation and prediction of high-pressure phase equilibrium in systems containing supercritical carbon dioxide and a salt. I will further simplify the question: if the solubility of NaCl in water at 25°C is 6.14 mol/L, why does NaCl's solubility in both a mixture (water+methanol) and a mixture (water+formamide) decrease compared to that in pure water? Dielectric Constant Table.xls Acetone (127° F) 17.7 Acetone (32° F) 1.0159 Acetonitrile (70° F) 37.5 Acetophenone (75° F) 17.3 Acetoxime (24° F) 3 Anastasia Salameh, Flora Vorka, and Vangelis Daskalakis . Currently I'm doing some FTIR analysis to identify types of plastics. Hugh D. Burrows, Sofia M. Fonseca, Claudia L. Silva, Alberto A. C. C. Pais, María J. Tapia, Swapna Pradhan, Ullrich Scherf. Chapter 7 All-Inorganic Colloidal Silicon Nanocrystals. Hoefnagel, B.M. Maya. : Physico-chemical study of N-methyl-2-pyrrolidone-methanol system. Ryota Saito, Yuriko Matsumura, Saori Suzuki, Naoki Okazaki. Nabin Basnet, Sushila Prasai, Hector Dominguez, Marlene Ríos-López, Rajendra Adhikari, Madhav Prasad Ghimire. Gast, E. Gast, W. Maier, A. W. Fink, E. Truscheit. He's on researchgate too. The dielectric constants were determined by using a new setup based on a low-pass filter. Berichte der Bunsengesellschaft für physikalische Chemie. DOS had a lowering effect of DOC and the effect became more remarkable in the solvent of high ε. I think the following below link may help you in your analysis: Thank you very much for your quick and kind reply. Resch. Wee Shan Tay, Yunpeng Lu, Xiang‐Yuan Yang, Yongxin Li, Sumod A. Pullarkat, Pak‐Hing Leung. I've gone through many articles, with most results presented in %T while others in Abs. Demethylation Kinetics of Aspartame in Binary Aqueous-Organic Solvents. Dear Colleagues (Simon Müller, Poorya Mobalegholeslam, Mohd Farid Ismail, …). Thermospray liquid chromatographic—mass spectrometric multi-residue determination of 128 polar pesticides in aqueous environmental samples. This is the reason wha in the last response I said, that the balance between the short range and the long range interactions is important. Language problems: I don't think you've understood me or I've understood you. (all with lower dielectric constant than water and therefore also the mixture). Fluid Phase Equilib. I know more about thermodynamic modelling than applying QSPR approaches for predicting solubility of salts in mixed solvent systems, so I will concentrate on this (. En el documento adjunto, he buscado algunos sistemas que muestran la solubilidad en fracción de peso y en fracción molar de algunas sales alcalinas. In a different paper, I used data on a different polymer. In addition, _in my opinion_ the reason why thermodynamic model is less useful for some people, is because it provides no guidance on how to select a particular solvent (or solvent components in binary or higher solvent mixtures) just based on the solvent property (or properties).